Codex Sinaiticus
The Codex Sinaiticus, designated by siglum א [Aleph] or as the Sinai Bible. It appearsin the fourth century as a Christian manuscript of a Greek Bible, containing the majority of the Greek Old Testament, including the Apocrypha and other deuterocanonical books, and the Greek New Testament, with both the Epistle of Barnabas and the Shepherd of Hermas included.
Of course controversies arise over omitted verses.